Advanced Hybridization and Exercises

This section expands on the concept of hybridization, focusing on more complex inorganic compounds and introducing exercises to apply the learned concepts.

The document discusses advanced hybridization schemes involving d orbitals:

1. PF5 (Phosphorus pentafluoride) exhibits sp3d hybridization, resulting in a trigonal bipyramidal structure with five domains.
2. SF6 (Sulfur hexafluoride) shows sp3d2 hybridization, leading to an octahedral geometry with six domains.

Example: In SF6, the sulfur atom uses its 3s, 3p, and two 3d orbitals to form six equivalent sp3d2 hybrid orbitals, allowing it to bond with six fluorine atoms in an octahedral arrangement.

The page then transitions to practical exercises, focusing on determining the molecular geometry and polarity of complex ions like [ICl6]-.

Highlight: The exercise on [ICl6]- demonstrates how to apply teoría de enlace de valencia and hybridization concepts to predict the structure of complex ions, considering factors such as the central atom's electronic configuration and the number of bonding and lone pair domains.

The document concludes by mentioning that the [ICl6]- ion has a square planar geometry with 180° and 90° bond angles, and is non-polar. This example serves to reinforce the importance of understanding hybridization and molecular geometry in predicting the properties of compuestos inorgánicos.

Theory of Valence Bond

The theory of valence bond explains the formation of covalent bonds through the superposition of atomic orbitals from different atoms and the pairing of electrons. This section introduces the concept of sigma and pi bonds, which are fundamental to understanding molecular structures.

Definition: A sigma bond is formed by the head-on overlap of atomic orbitals, resulting in the highest electron density between the nuclei of bonded atoms.

The document provides examples of sigma bonds in simple molecules like H2 and more complex ones like O2 and N2. It also introduces the concept of pi bonds, which are formed by the side-by-side overlap of p orbitals.

Example: The nitrogen molecule (N2) demonstrates both sigma and pi bonding. It has one sigma bond and two pi bonds, resulting in a triple bond between the nitrogen atoms.

The page concludes with a brief mention of the electronic configuration of oxygen, setting the stage for further discussion on molecular structures and bonding theories.